Metal homoenolate chemistry. Isolation and reactions of titanium homoenolates of esters

E Nakamura, I Kuwajima

文献索引：Nakamura,E.; Kuwajima,I. Journal of the American Chemical Society, 1983 , vol. 105, p. 651

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被引用次数: 52

摘要

(2) Because of the general lack of serious concern about the chemistry of metal homoenolates (except their synthetic equivalents), the word'homoenolate" has been related only loosely to the carbon anion 1. Etymologically, however," homoenolate" anion should mean the oxygen anion 2, similar to the case of" enolate". In spite of such formalism, we prefer using" metal homoenolate" as the term for 1; for 2 is more commonly called ...