Application of photoelectron spectroscopy to molecular properties. Part 41. Flash vacuum thermolysis of 2, 3-dihydro-1, 4-oxathiin: synthesis, photoelectronic …

…, Y Vallee, S Lacombe, G Pfister-Guillouzo

文献索引：Bourdon, Francois; Ripoll, Jean-Louis; Vallee, Yannick; Lacombe, Sylvie; Pfister-Guillouzo, Genevieve Journal of Organic Chemistry, 1990 , vol. 55, # 9 p. 2596 - 2600

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被引用次数: 11

摘要

Thioxoethanal has been generated in the gas phase by flash vacuum thermolysis of 2, 3- dihydro-1, 4-oxathiin. Its characterization was performed by chemical trapping and photoelectron spectroscopy (PES). The PE HeI-He11 study led to the conclusion that thiooxethanal was obtained, with ethylene, as the only thermolysis product at 720" C. At higher temperatures, a cleavage into methanethial and carbon monoxide was observed. ...