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Synthesis and characterization of well-defined l-lactic acid-caprolactone co-oligomers and their rhenium (I) and technetium (I) conjugates

H Zhu, Z Yang, N Li, XJ Wang, F Wang, H Su…

文献索引:Zhu, Hua; Yang, Zhi; Li, Nan; Wang, Xue-Juan; Wang, Feng; Su, Hua; Xie, Qing; Zhang, Yan; Ma, Yun-Xia; Lin, Bao-He Journal of Organometallic Chemistry, 2012 , vol. 716, p. 95 - 102

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被引用次数: 1

摘要

Staring from l-lactide and ε-caprolactone, the corresponding lactic-caprolactone cooligomer with hydroxyl and carboxylic acid groups were synthesized. These oligomers were connected with chelating groups through a long chain tether, ready for transition metal binding. Coordination of organometallic rhenium (I) and technetium (I) complexes generated the conjugates in high yield and short time, satisfying the requirements for short-lived ...