Inorganic Chemistry

Studies on nickel (II) complexes of cyclam ligands containing functionalized nitrogen substituents: synthesis, isomerization, and N-dealkylation

…, EK Barefield, DG Van Derveer

文献索引：Freeman, Gary M.; Barefield, E. Kent; Derveer, Donald G. Van Inorganic Chemistry, 1984 , vol. 23, p. 3092 - 3103

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被引用次数: 61

摘要

Macrocyclic ligands that contain tertiary nitrogen donors represent a relatively unstudied class of metal complexing agent. On the basis of the limited information that is currently available, it appears that the conversion of secondary amines to tertiary amines in a macrocyclic ligand decreases its effective ligand field strength.* As a result, the redox and spectral properties of a metal complex can be" tuned" over a considerable range by ...