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One-pot and efficient electrosynthesis of cycloalkylphosphonates from diisopropyl trichloromethylphosphonate using magnesium electrochemical activation

P Jubault, C Feasson, N Collignon

文献索引：Jubault, Philippe; Feasson, Christian; Collignon, Noel Tetrahedron Letters, 1996 , vol. 37, # 21 p. 3679 - 3682

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被引用次数: 4

摘要

Various diisopropyl cycloalkylphosphonates were easily prepared in an one-pot sequence under mild conditions, by electrolysing diisopropyl trichloromethylphosphonate in the presence of ω, ω-dibromoalkanes. The use of an electrochemical activated magnesium amode significantly improved the rate and the yield of the two first steps of the reaction.