Chemistry Letters

Vinyl migration in the oxythallation of some 1, 3-dienes.

M Murakami, S Nishida

文献索引：Murakami, Masashi; Nishida, Shinya Chemistry Letters, 1981 , p. 997 - 1000

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被引用次数: 6

摘要

The oxythallation of certain 1, 3-dienes with thallium (III) nitrate trihydrate in MeOH–CH 2 Cl 2 at 0–20° C gave products after vinyl migration. Methyl 1-methylcyclopropyl ketone, obtained in the reaction of 2, 3-dimethyl-1, 3-butadiene, was presumably derived from a cyclopropylmethyl cation, an intermediate in the vinyl migration.