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Bis-(polyfluoroalkyl)-acetylenes. V. Addition of Bis-(trifluoromethyl)-1, 2-dithietene to Olefins and Acetylenes1

CG Krespan, BC McKusick

文献索引:Krespan,C.G.; McKusick,B.C. Journal of the American Chemical Society, 1961 , vol. 83, p. 3438 - 3440

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被引用次数: 31

摘要

This ditliietene adds to acetylenes to form p-dithiins, thiophenes and dihydro-p-dithiino-, h- ditliiins, with the products formed dependent on reaction temperature and electronegativity of substituents on the acetylenic bond. Bis-(trifluoromethyl)-1, 2-dithietene also combines with mercury to form a reactive mercuric salt.