Stereoselective synthesis of alkenes and alkenyl sulfides from alkenyl halides using palladium and ruthenium catalysts

S Murahashi, M Yamamura…

文献索引：Murahashi,S.-I. et al. Journal of Organic Chemistry, 1979 , vol. 44, # 14 p. 2408 - 2417

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被引用次数: 303

摘要

Alkenyl halides react with organolithium compounds, such as alkyl, aryl, and heterocyclic lithiums, in the presence of zerovalent palladium compounds to form alkenes stereoselectively under both stoichiometric and catalytic conditions. Alkenyl halides also are easily converted to the corresponding alkenyl sulfides stereoselectively upon treatment with thiolate anions in the presence of the same palladium catalyst. These reactions occur ...