Thermolysis and acid-catalyzed decomposition of 4-diazotetrahydrofuran-3-ones. A new efficient synthesis of tetrasubstituted dihydrofuran-3-ones

…, YY Medvedev, PN Moroz, VA Nikolaev

文献索引：Rodina; Medvedev; Moroz; Nikolaev Russian Journal of Organic Chemistry, 2012 , vol. 48, # 4 p. 602 - 604

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被引用次数: 3

摘要

The Wolff rearrangement is one of the most characteristic transformations of diazo ketones [1]. Diazo ketones of the tetrahydrofuran series are thus converted into oxetane derivatives. Using tetramethylsubstituted diazotetrahydrofuranone as an example, we previously showed [2] that its photolytic Wolff rearrangement was the most efficient [2]. Photoinduced reactions of aryl-substituted diazotetrahydrofuranones are characterized by lower ...