Inorganic chemistry

Solid-to-Solid Oxidation of a Vanadium (IV) to a Vanadium (V) Compound: Chemisty of a Sulfur-Containing Siderophore

PB Chatterjee, DC Crans

文献索引：Chatterjee, Pabitra B.; Crans, Debbie C. Inorganic Chemistry, 2012 , vol. 51, # 17 p. 9144 - 9146

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被引用次数: 6

摘要

Visible light facilitates a solid-to-solid aerial oxidation of a hunter-green oxidovanadium (IV) complex to form a black powder of cis-dioxidovanadium (V) complex. The tridentate sulfur- containing ligand used in this study is a siderophore. This irreversible transformation of a metal oxo species to a metal dioxo in the presence of oxygen extends solid matrix chemistry to include oxidation reactions and is the first example of its class.