The Journal of Organic Chemistry

Allylic Chlorides. XXVII. The Relative Reactivities of γ-Alkylallyl Chlorides

LF Hatch, TP Li

文献索引：Hatch,L.F.; Li,T.P. Journal of Organic Chemistry, 1963 , vol. 28, p. 2400 - 2403

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被引用次数: 2

摘要

Rate and thermodynamic data are presented for the reaction between both potassium iodide in acetone and sodium ethoxide in ethanol and the following allyl chlorides: allyl chloride, cis-and trans-y-methylallyl chloride, cis-and trans-y-ethylallyl chloride, cis-and trans-r- isopropylallyl chloride. All of the y-alkylallyl chlorides were more reactive than allyl chloride and the cis isomer was more reactive than the trans isomer, especially with potassium ...