Journal of Organometallic Chemistry

Phosphinigsa¨ ure-silyl-,-germanyl-,-stannylester des typs (R2PO) nER′ 4− n

K Issleib, B Walther

文献索引：Issleib,K.; Walther,B. Journal of Organometallic Chemistry, 1970 , vol. 22, p. 375 - 386

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被引用次数: 31

摘要

Abstract Phosphinous acid esters of the type (R 2 P single bond O single bond) n ER′ 4− n (E= Si, Ge, Sn) are prepared by three different methods: 1. reaction of the alkali-phosphinites with R′ 3 ECl, 2. reaction of the sec-phosphine oxides with organochlorosilanes in the presence of triethylamine, 3. reaction of the sec-phosphine oxides with organotin amides. The reactions of these compounds with H 2 O 2, sulfur, H 2 O, CH 3 I, HgBr 2, SOCl 2, CS ...