Synthesis and reactions of (. eta. 5-cyclopentadienyl) tricarbonylhydridovanadate. A comparative mechanistic study of its organic halide reduction reactions with those …
RJ Kinney, WD Jones, RG Bergman
文献索引：Kinney,R.J. et al. Journal of the American Chemical Society, 1978 , vol. 100, # 25 p. 7902 - 7915
Abstract: The complex PPN+[CpV (C0) 3H]-(PPN-3; Cp q5-C5H5) has been prepared in 70% yield by sodium reduction of CpV (CO) 4 (1) followed by protonation of the resulting dianion [CpV (CO),]*-(2) with water and cation exchange with PPN+ CI-. The physical properties and chemical reactions of 3 have been investigated. The sodium salt of 3 is contact ion paired in the solid state and in THF; dissociation of solvent-separated pairs ...
