Synthesis

Synthesis of gymnoascolide A

MM Baag, NP Argade

文献索引：Baag, Md. Merajuddin; Argade, Narshinha P. Synthesis, 2008 , # 1 p. 26 - 28

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被引用次数: 4

摘要

Abstract Recently isolated 4-benzyl-3-phenylfuran-2, 5-dione and antifungal gymnoascolide A have been synthesized using the chemoselective SN 2′ coupling of phenylmagnesium bromide with dimethyl 2-(bromomethyl) fumarate, chemoselective allylic substitution of bromide in 3-(bromomethyl)-4-phenylfuran-2, 5-dione with phenylmagnesium bromide and regioselective N-Selectride-induced reduction of 3-benzyl-4-phenylfuran-2, 5-dione as the ...