Synthesis and characterization of new, modified terphenyl ligands: Increasing the rotational barrier for flanking rings
C Stanciu, AF Richards, JC Fettinger, M Brynda…
文献索引：Stanciu, Corneliu; Richards, Anne F.; Fettinger, James C.; Brynda, Marcin; Power, Philip P. Journal of Organometallic Chemistry, 2006 , vol. 691, # 11 p. 2540 - 2545
The synthesis and characterization of some new terphenyl ligands, modified by meta alkyl substitution on the central ring are described. The new ligands were designed for potential applications in the stabilization of novel low valent main group species or transition metal heteronuclear multiply bonded compounds. Compounds 1-I-C6H1-2, 6-Ph2-3, 5-Pr2i (1), 1-I- C6H1-2, 6-Mes2-3, 5-Pr2i (3)(Mes= 2, 4, 6-trimethylphenyl), 1-I-C6H1-2, 6-Trip2-3, 5-Pr2i ( ...
