A novel alkenyl-substituted ansa-zirconocene complex with dual application as olefin polymerization catalyst and anticancer drug

S Gómez-Ruiz, GN Kaluđerović, D Polo-Cerón…

文献索引：Gomez-Ruiz, Santiago; Kaluderovic, Goran N.; Polo-Ceron, Dorian; Tayurskaya, Valentina; Prashar, Sanjiv; Fajardo, Mariano; Paschke, Reinhard Journal of Organometallic Chemistry, 2009 , vol. 694, # 18 p. 3032 - 3038

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被引用次数: 14

摘要

The alkenyl substituted fulvene compound,(C5H4) CMe (CH2CH2CHCMe2)(1), reacts with one equivalent of LiMe to give the lithium derivative Li {C5H4 (CMe2CH2CH2CHCMe2)}(2). The reaction of 2 with Me2Si (C5Me4H) Cl gave the ansa-ligand precursor Me2Si (C5Me4H)(C5H4 (CMe2CH2CH2CHCMe2))(3), which after the subsequent reaction with 2 equivalents of LiBun yielded the dilithium salt Li2 {Me2Si (C5Me4)(C5H3 ( ...