The influence of ion-pairing on the electroreductive cleavage of substituted 9, 10-anthraquinones in DMF solution
RL Blankespoor, DL Schutt, MB Tubergen…
文献索引：Blankespoor, Ronald L.; Schutt, David L.; Tubergen, Melinda B.; De Jong, Randy L. Journal of Organic Chemistry, 1987 , vol. 52, # 10 p. 2059 - 2064
A variety of substituted 9, lO-anthraquinones with acetate and trifluoroacetate leaving groups at the 2-methyl position were synthesized from 2-methyl-9, lO-anthraquinones containing 0- 2 methoxy substituents. Cyclic voltammograms of the acetates in DMF containing LiC104 as supporting electrolyte exhibited two reduction waves, the first resulting from the formation of Li+ ion pairs of their radical anions and the second from Li+ ion pairs of their dianions. ...
