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Creation of a mixed-valence state from one-dimensionally aligned TTF utilizing the self-assembling nature of a low molecular-weight gel

…, S Kawano, U Beginn, N Fujita, S Shinkai

文献索引:Kitahara, Tatsuya; Shirakawa, Michihiro; Kawano, Shin-Ichiro; Beginn, Uwe; Fujita, Norifumi; Shinkai, Seiji Journal of the American Chemical Society, 2005 , vol. 127, # 43 p. 14980 - 14981

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被引用次数: 148

摘要

Tetrathiafulvalene (TTF) 1 is known as an organic conductive material whose high electron conductivity is originated from their π-stacked columnar structures in its single crystals. 2 Reducing the dimensional parameters of the bulk materials matrix from the three-dimensional crystal structure into the one-dimensional columnar structure gathers strong attention since this concept would furnish the functional nanowires 3 which are key materials in advanced nanosciences. Recently, ...