Fluxional cyclopropanones. Approaching measurable equilibrium concentrations of acyclic oxyallyls

TS Sorensen, F Sun

文献索引：Sorensen, Theodore Strang; Sun Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 5 p. 1053 - 1061

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被引用次数: 0

摘要

The preparation of five new cis-2, 3-di-R-cyclopropanones is described where R= tert-amyl, thexyl, 2-(2, 3, 3-trimethylbutyl), 1-adamantyl and 1-(7, 7-dimethylnorbornyl). As structure proof for these labile compounds, the [3+ 4] furan adducts were characterized, and the cis cyclopropanones were also converted into th