Beyond Benzyl Grignards: Facile Generation of Benzyl Carbanions from Styrenes
…, R Van Hoveln, S Neale, JM Schomaker
文献索引：Grigg, R. David; Rigoli, Jared W.; Van Hoveln, Ryan; Neale, Samuel; Schomaker, Jennifer M. Chemistry - A European Journal, 2012 , vol. 18, # 30 p. 9391 - 9396
Abstract Benzylic functionalization is a convenient approach towards the conversion of readily available aromatic hydrocarbon feedstocks into more useful molecules. However, the formation of carbanionic benzyl species from benzyl halides or similar precursors is far from trivial. An alternative approach is the direct reaction of a styrene with a suitable coupling partner, but these reactions often involve the use of precious-metal transition-metal ...
