Pd??PEPPSI??IPent: Low??Temperature Negishi Cross??Coupling for the Preparation of Highly Functionalized, Tetra??ortho??Substituted Biaryls

…, M Sayah, D Mallik, MG Organ

文献索引：Calimsiz, Selcuk; Sayah, Mahmoud; Mallik, Debasis; Organ, Michael G. Angewandte Chemie - International Edition, 2010 , vol. 49, # 11 p. 2014 - 2017

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被引用次数: 95

摘要

Biaryls are important motifs seen in the structures of many biologically active compounds and organic materials. Thus, the development of efficient bond-forming procedures between sp2-hybridized carbon atoms has been pursued intensively by both academic and industrial scientists.[1] The synthesis of biaryl compounds began with the century-old Ullmann reaction [2] and has evolved into a wide variety of Niand Pd-catalyzed cross-coupling procedures.[ ...