Investigations in the Acetylene Series. I. The Reactions of 3-Methyl-1-butyn-3-ol with Phosphorus Trichloride and of 3-Methyl-3-buten-1-yne with Hydrochloric Acid

ED Bergmann, D Herrman

文献索引：Bergmann; Herrman Journal of the American Chemical Society, 1951 , vol. 73, p. 4013

全文：HTML全文

被引用次数: 11

摘要

4-Methyl44 5, 6, 7, I-tetrahydro-p-naphthacy1)-morpho-Mum Iodide.-5, 6, 7, S-Tetrahydro-p- naphthacyl bromide was prepared in 43% yield by dropwise addition of a mixture of 204 g. of bromoacetyl bromide (1.01 moles) and 120 g. of tetralin (0.91 mole) in 600 ml. of carbon disulfide to 150 g. of aluminum chloride (1.13 moles) in 1200 ml. of carbon disulfide at 0-IO', stirring 2 hours, and decomposing with ice and dilute hydrochloric acid, mp 69'after ...