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Different enantioselective interaction pathways induced by derivatized quinines

G Uccello-Barretta, F Balzano…

文献索引:Uccello-Barretta, Gloria; Balzano, Federica; Quintavalli, Cristiana; Salvadori, Piero Journal of Organic Chemistry, 2000 , vol. 65, # 12 p. 3596 - 3602

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被引用次数: 26

摘要

The stereochemistries in solution of the diastereoisomeric complexes formed by quinines modified at the hydroxyl site (9-O-acetylquinine; 9-O-(3, 5-dimethoxyphenylcarbamate) quinine) or quinuclidine nitrogen (N-benzylquininium chloride) and each enantiomer of 2-(3', 5'-dinitrobenzamido)-1-phenylethanol have been compared to those of the free compounds by 1H NMR investigations. Completely different interaction models, also involving ...