Journal of the Indian Chemical Society

Oxidative deprotection of oximes, phenylhydrazones and semicarbazones using pyridinium chlorochromate in catalytic amount with t-butyl hydroperoxide and in the …

NC Ganguly, M Datta, P De

文献索引：Ganguly, Nemai C.; Datta, Mrityunjoy; De, Prithwiraj Journal of the Indian Chemical Society, 2004 , vol. 81, # 4 p. 308 - 312

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被引用次数: 5

摘要

Résumé/Abstract Pyridinium chlorochromate (PCC) and other oxochromium (vt) reagents have been extensively employed in excess of the stoichiometric amount (2 equivalents or more) for efficient cleavage of oximes to carbonyl compounds. The aim of this study is to replace excess use of toxic chromium (VI) reagents and develop cleaner environment- friendly general methods of cleavage of imine derivatives such as oximes, ...