Journal of Organometallic Chemistry

Synthesis of acylsilanes via oxidative hydrolysis of 2-silyl-1, 3-dithianes mediated by N-bromosuccinimide

AF Patrocı́nio, PJS Moran

文献索引：Patrocinio, Amauri F.; Moran, Paulo J.S. Journal of Organometallic Chemistry, 2000 , vol. 603, # 2 p. 220 - 224

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被引用次数: 40

摘要

The oxidative method for the hydrolysis of 1, 3-dithianes was applied to 2-silyl-1, 3-dithianes using N-bromosuccinimide providing acylsilanes with good yields under a short reaction period. The oxidation of aroylsilanes to carboxylic acid was prevented by the addition of bases and the lowering of the reaction temperature.