New carbon-phosphorus macrocycles

F Mathey, F Mercier, P Le Floch

文献索引：Mathey, Francois; Mercier, Francois; Le Floch, Pascal Phosphorus, Sulfur and Silicon and Related Elements, 1999 , vol. 144-146, p. 251 - 256

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被引用次数: 3

摘要

The synthesis of several phosphole and phosphinine-based macrocycles is described. The first ones are flexible as a result of the low inversion barrier of phosphorus. The mixture of isomers can be directly used in coordination chemistry. The second ones are not plagued by conformational problems and display strong π-acceptor properties.