Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates

M Kawatsura, F Ata, S Wada, S Hayase…

文献索引：Kawatsura, Motoi; Ata, Fumio; Wada, Shohei; Hayase, Shuichi; Uno, Hidemitsu; Itoh, Toshiyuki Chemical Communications, 2007 , # 3 p. 298 - 300

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被引用次数: 15

摘要

Transition metal-catalysed allylic substitution is a useful process in organic synthesis, and many excellent results have been reported for the reaction of symmetrically disubstituted substrates. 1 On the other hand, the regioselective allylic substitution of unsymmetrical allyl substrates is a difficult problem and very challenging topic in this field of chemistry. In particular, it is known that the control of mono-substituted allyl substrates that forms both linear and branched ...