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Hyperbranched Polyfluorinated benzyl ether polymers: Mechanism, kinetics, and optimization

MJ Quast, A Mueller

文献索引:Quast, Matthew J.; Mueller, Anja Journal of Polymer Science, Part A: Polymer Chemistry, 2014 , vol. 52, # 7 p. 985 - 994

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被引用次数: 3

摘要

ABSTRACT Highly fluorinated, hyperbranched polymers were synthesized from the polycondensation of AB 2 monomers, 3, 5-bis [(pentafluorobenzyl) oxy] benzyl alcohol and 3, 5-bis [(pentafluorobenzyl)-oxy] phenol with potassium carbonate base, and 18-crown-6 phase transfer agent in a variety of polar aprotic solvents. The regioselectivity of the polymerization was optimized and was found to be temperature dependent. The new ...