The Activation of Bivalent Sulfur Compounds with Cupric Chloride and Zinc Chloride. The Benzylation and Acylation of Aromatic Compounds with Sulfides and Thiol …
K Maekawa, K Narasaka, T Mukaiyama
文献索引：Maekawa,K. et al. Bulletin of the Chemical Society of Japan, 1973 , vol. 46, p. 3478 - 3481
Benzylation of aromatic compounds, such as anisole, m-xylene, toluene, and benzene, with various benzyl sulfides in the presence of equimolar amounts of cupric chloride and zinc chloride was investigated. For example, in the case of benzylation of anisole with 4- benzylthiopyridine, o-and p-benzylanisoles were obtained in 79% yield in the presence of cupric chloride and zinc chloride. On the other hand, when the reaction was carried out in ...
