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Journal of Organometallic Chemistry

Reactions of triethylsilyl thiophenoxide with ketones having an electron-with-drawing group on the α-carbon

I Ojima, Y Nagai

文献索引:Ojima,I.; Nagai,Y. Journal of Organometallic Chemistry, 1973 , vol. 57, p. C42 - C44

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被引用次数: 22

摘要

Abstract Triethylsilyl thiophenoxide has been found to react with easily enolizable ketones to give silyl enol ethers; these have also been synthesized by a Rh I complex catalysed reaction of triethylsilane with enolizable ketones in the presence of a small amount of silyl thioether or thiophenol.