Aqueous self-assembly of an electroluminescent double-helical metallopolymer

X de Hatten, D Asil, RH Friend…

文献索引：De Hatten, Xavier; Asil, Demet; Friend, Richard H.; Nitschke, Jonathan R. Journal of the American Chemical Society, 2012 , vol. 134, # 46 p. 19170 - 19178

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被引用次数: 27

摘要

A new type of water-soluble copper-containing polymer has been synthesized using the technique of subcomponent self-assembly. Copper (I)-directed imine bond formation between triethylene glycol functionalized 1, 2-phenylenediamine and 2, 9- diformylphenanthroline subcomponents resulted in the formation of a chain in which two conjugated helical ligand strands wrap around a linear array of metal ions. ...