Organic letters

cis-2, 5-Diaminobicyclo [2.2. 2] octane, a New Scaffold for Asymmetric Catalysis via Salen− Metal Complexes

JD White, S Shaw

文献索引：White, James D.; Shaw, Subrata Organic Letters, 2011 , vol. 13, # 9 p. 2488 - 2491

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被引用次数: 29

摘要

A new C 2 symmetric salen scaffold based on cis-2, 5-diaminobicyclo [2.2. 2] octane has been synthesized that forms complexes with a wide range of metals. The chromium (III) complex is shown to catalyze the hetero-Diels− Alder reaction and the Nozaki− Hiyama− Kishi reaction with high efficiency and excellent stereoselectivity.