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Polar ligand adsorption controls semiconductor surface potentials

M Bruening, E Moons, D Yaron-Marcovich…

文献索引:Bruening; Moons; Yaron-Marcovich; Cahen; Libman; Shanzer Journal of the American Chemical Society, 1994 , vol. 116, # 7 p. 2972 - 2977

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被引用次数: 99

摘要

Abstract: Controlled surface modification of CdTe single crystals and CdTe and CuInSez solar cell quality thin films was achieved by chemisorption of a series of organic ligands with varying dipole moments. Contact potential difference measurements in air showed that adsorption of benzoic or hydroxamic acid derivatives on the thin films or crystals changes the semiconductors' electron affinity without significantly affecting band bending. The ...