Assessing the Effect of Ligand Proximity on Chiroptical and Other Properties in Cobalt (III) Model, Tyrosine-Like Complexes

F Jursík, RD Archer

文献索引：Jursik, Frantisek; Archer, Ronald, D. Collection of Czechoslovak Chemical Communications, 1995 , vol. 60, # 12 p. 2097 - 2106

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被引用次数: 5

摘要

Abstract A series of new cobalt (III) octahedral complexes of the general formula Na [Co (ohb- aa) 2](ohb-aa= N-(o-hydroxybenzyl) amino acid anion); amino acid= glycine,(S)-α-alanine, α- aminoisobutyric acid,(S)-valine,(S)-norvaline and (S)-leucine) were prepared by the charcoal catalyzed reaction of the appropriate ligand with [Co (NH 3) 6] 3+ in alkaline aqueous solution. Complexes obtained have, regardless of the amino acid used, the ...