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Tautomerism of 2??amino??2??oxazolin??4??ones. II

G Rapi, M Ginanneschi, E Belgodere…

文献索引:Rapi,G. et al. Journal of Heterocyclic Chemistry, 1972 , vol. 9, p. 285 - 292

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被引用次数: 10

摘要

Abstract The study of the tautomerism of 2-amino-2-oxazolin-4-one (1) and its methyl derivatives has been completed. The methylation of 1 gave 2-imino-3-methyloxazolidin-4- one (4) and 2-methyl-amino-2-oxazolin-4-one (7). All attempts to isolate O-methyl derivatives failed. The uv, nmr, ir, and Raman spectra led to the definite conclusion, in agreement with the chemical evidence, that the 2-aminooxazolinic form a, if it is ...