The Journal of Organic Chemistry

Phosphonic acids and esters. XIX. Synthesis of substituted phenyl-and arylphosphonates by the photoinitiated arylation of trialkyl phosphites

R Obrycki, CE Griffin

文献索引：Obrycki,R.; Griffin,C.E. Journal of Organic Chemistry, 1968 , vol. 33, p. 632 - 636

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被引用次数: 47

摘要

The syntheses of a variety of nuclear substituted (methyl, ethyl, methoxy, hydroxy, amino, formyl) phenylphosphonates 3 and other aryl-(1-naphthyl-, 2-thienyl-, 2-furyl-) phosphonates have been carried out by the lowtemperature ultraviolet photolyses of the corresponding aryl iodides in excess trialkyl (methyl or ethyl) phosphite 1. The process constitutes an experimentally simple one-step procedure for the synthesis of these compounds in good ...