Bulletin of the Chemical Society of Japan

Thermal and Photolytic Decompositions of Azobis (2-phenoxy)-2-propane

A Ohno, N Kito, Y Ohnishi

文献索引：Ohno,A. et al. Bulletin of the Chemical Society of Japan, 1971 , vol. 44, p. 467 - 470

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被引用次数: 13

摘要

Thermal and photolytic decompositions of azobis (2-phenoxy)-2-propane have been studied. More than half of the 2-phenoxyprop-2-yl radicals thus produced thermally cause the phenyl group to migrate from oxygen to the carbon, followed by elimination of the methyl group. Most of the remaining radicals abstract hydrogen from the solvent. When phenyl ether is employed as a solvent, homolytic aromatic substitution takes place yielding ...