Some novel reactions of N-chlorodifluoromethanimine

…, CW Bauknight Jr, DD DesMarteau

文献索引：Zheng, Yuan Y.; Bauknight, Charles W.; DesMarteau, Darryl D. Journal of Organic Chemistry, 1984 , vol. 49, # 19 p. 3590 - 3595

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被引用次数: 8

摘要

Some reactions of N-chlorodifluoromethanimine, CFz= NC1, have been studied and are compared to related reactions of perfluoromethanimine, CF2= NF. Fluoride promoted reactions of CF2= NC1 result in evidence for the CF3NC1-anion, which is thermally less stable and less reactive than CF3NF-. Oxidation of CF3NCl-, formed in situ by reaction of CFz= NC1 with KF or CsF, with Clz forms CF3NC12 With Brz, CF3NBrCl is formed along ...