Production of nitrogen monochloride (a) by thermal decomposition of chlorine azide

DJ Benard, MA Chowdhury, BK Winker…

文献索引：Benard, D. J.; Chowdhury, M. A.; Winker, B. K.; Seder, T. A.; Michels, H. H. Journal of Physical Chemistry, 1990 , vol. 94, # 19 p. 7507 - 7514

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被引用次数: 42

摘要

Thermal decompition of C1N3 by pulsed C 0 2 laser pyrolysis has been investigated by using SF, as a sensitizer. The electronically excited decomposition products, NCl (a) and NCl (b), were monitored by absolute time-resolved emission spectroscopy while CIN3 was followed by ultraviolet absorption. The results indicate a higher barrier to dissociation of CIN, than FN3, consistent with ab initio calculations, and an NCl (a) yield of order unity, based ...