前往化源商城

Reactions of polychlorobenzenes with alkanethiol anions in HMPA. A simple, high-yield synthesis of poly (alkylthio) benzenes

L Testaferri, M Tingoli, M Tiecco

文献索引:Testaferri, Lorenzo; Tingoli, Marco; Tiecco, Marcello Journal of Organic Chemistry, 1980 , vol. 45, # 22 p. 4376 - 4380

全文:HTML全文

被引用次数: 80

摘要

Reactions of the isomeric trichlorobenzenes and tetrachlorobenzenes and of pentachloro- and hexachlorobenzene with an excess of the sodium salt of the isopropanethiol, in HMF'A, afforded the products of complete displacement of all the chlorine atoms present in the molecule. Similar substitutions were also obtained with EtSNa. The reactions with MeSNa were in some cases complicated by the competitive nucleophilic attack at the methyl ...