Transition metal complexes incorporating the BF 2 ligand formed by oxidative addition of the B–B bond in B 2 F 4

N Lu, NC Norman, AG Orpen, MJ Quayle…

文献索引：Lu, Norman; Norman, Nicholas C.; Guy Orpen; Quayle, Michael J.; Timms, Peter L.; Whittell, George R. Journal of the Chemical Society, Dalton Transactions, 2000 , # 22 p. 4032 - 4037

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被引用次数: 16

摘要

The reactions between B2F4 and the platinum and iridium complexes [Pt (PPh3) 2 (η- C2H4)],[Pt (dppb)(η-C2H4)][dppb= 1, 4-bis (diphenylphosphino) butane] and trans-[IrCl (CO)(PPh3) 2] afforded the difluoroboryl complexes cis-[Pt (BF2) 2 (PPh3) 2], cis-[Pt (BF2) 2 (dppb)] and fac-[Ir (BF2) 3 (CO)(PPh3) 2] respectively all of which have been characterised by X-ray crystallography. The isoelectronic platinum dppb nitrito complex cis-[Pt (NO2) 2 ( ...