Reactivity of Monolithium Bis (trimethylsily) hydrazine towards carbon and tin halides

PK Verma

文献索引：Verma, P. K. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1991 , vol. 605, p. 131 - 136

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被引用次数: 3

摘要

Abstract Monolithium bis (trimethylsilyl) hydrazine LiHN 2 (SiMe 3) 2 (1) undergoes disproportionation in THF. Compound (1) reacts with CCl 4 to provide bis (trimethylsily) aminocarbonimidic dichloride whereas CBr 4 behaves exclusively as an oxidant. Compound (1) as a strong base towards haloalkanes like CHCl 3, CHI 3, CH 2 I 2 and CH 2 Cl 2. Also reaction of (1) with CHCl 3 provides N, N-bis (trimethylsilyl)- ...