One-pot conversions of (silylmethyl) cyclopropanes to homoallylic alcohols and 1, 4-diols based on haloborane-induced ring opening

…, A Hirai, H Suzuki, N Sonoda, S Murai

文献索引：Ryu, Ilhyong; Hirai, Akira; Suzuki, Haruhisa; Sonoda, Noboru; Murai, Shinji Journal of Organic Chemistry, 1990 , vol. 55, # 5 p. 1409 - 1410

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被引用次数: 17

摘要

Summary: The reactions of (silylmethy1) cyclopropanes with haloboranes, such as BBr3 and BHBr2, result in desilylative ring opening to give homoallylboranes and boracyclopentanes, respectively. Coupled with subsequent oxidation procedure, these reactions provide ready access to homoallylic alcohols and 1, 6diols.