Tetrahedron

Stereocontrolled synthesis of α-trialkylsilyl-β, γ-unsaturated aldehydes via palladium (0) catalysis. Synthetic usefulness

F Le Bideau, F Gilloir, Y Nilsson, C Aubert, M Malacria

文献索引：Le Bideau; Gilloir; Nilsson; Aubert; Malacria Tetrahedron, 1996 , vol. 52, # 21 p. 7487 - 7510

全文：HTML全文

被引用次数: 27

摘要

The reaction of silicon substituted vinyloxiranes in the presence of catalytic amount of palladium (0) catalyst affords the title compounds. This new reaction proceeds smoothly, under very mild conditions and with complete chirality transfer. One-pot addition of selected organometallic nucleophiles to these aldehydes at very low temperature led to a highly selective preparation of the corresponding alcohols in very good yields. Influence of ...