Chemical Communications

Grignard reagents in ionic liquids

MC Law, KY Wong, TH Chan

文献索引：Law, Man Chun; Wong, Kwok-Yin; Chan, Tak Hang Chemical Communications, 2006 , # 23 p. 2457 - 2459

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被引用次数: 21

摘要

When we examined the reaction of magnesium metal with ethyl iodide in imidazolium based ionic liquid [bmim][BF 4 ] (1a), there was no reaction whatsoever, as expected. When [bdmim][BF 4 ] (1b) was used instead so that the acidic proton in the imidazolium moiety was replaced with a methyl group, a colour change from colorless to green and then red was observed at 80 °C. The reaction mixture however reverted to a colourless solution when the ...