Journal of the American Chemical Society

Novel 1, 2-migration reactions of organometals containing aluminum, zinc, and other main-group metals with. alpha.-haloorganolithiums

E Negishi, K Akiyoshi

文献索引：Negishi,E.; Akiyoshi,K. Journal of the American Chemical Society, 1988 , vol. 110, p. 646

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被引用次数: 50

摘要

I, 2-Migration or migratory insertion is, in principle, one of the most fundamental patterns for carbon-carbon and carbon-hetero atom bond formation. Indeed, the majority of carbon- carbon bond-forming reactions of organoboron compounds proceed via 1, 2-migrati0n.~ Carbonylation and related reactions of organo transition metals are representative examples of the 1, 2-migration reactions involving transition metal^.^ At present, however, relatively ...