Tetrahedron letters

An S RN 1 approach to some aromatic nitriles via diazosulfides

M Novi, G Petrillo, C Dell'Erba

文献索引：Novi, Marino; Petrillo, Giovanni; Dell'Erba, Carlo Tetrahedron Letters, 1987 , vol. 28, # 12 p. 1345 - 1348

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被引用次数: 13

摘要

Abstract: Diazosulfides L react with excess tetrabutylammonium cyanide in Me SO under photon (sunlamp) or electron (Pt cathode) stimulation to give the corresponding nitrl.? es. The results are interpreted on the basis of an S group. RN1 mechanism involving the (phenylthio) azo as nucleofugal