Tetrahedron

Efficient partial hydrogenation of trichloromethyl to gem-dichloromethyl groups in platinum on carbon-catalyzed system

…, T Imanishi, R Nakatani, Y Fujiwara, Y Monguchi…

文献索引：Sawama, Yoshinari; Imanishi, Takahiro; Nakatani, Ryosuke; Fujiwara, Yuta; Monguchi, Yasunari; Sajiki, Hironao Tetrahedron, 2014 , vol. 70, # 30 p. 4540 - 4546

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被引用次数: 5

摘要

Abstract While gem-dichloromethyl groups can be directly synthesized by the mono- dechlorination of the corresponding trichloromethyl groups, the suppression control of the over-reduction to form chloromethyl or methyl functionalities is quite difficult. We have established the efficient and widely applicable mono-dechlorination method of the trichloromethyl groups to form the corresponding gem-dichloromethyl groups using ...