The dichlorovinylation of enolates

AS Kende, M Benechie, DP Curran, P Fludzinski…

文献索引：Kende,A.S. et al. Tetrahedron Letters, 1979 , p. 4513 - 4516

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被引用次数: 20

摘要

The condensation of certain ketone and ester enolates with trichloroethylene proceeds with surprising ease to yield dichlorovinylation products. The stereochemistry for one such product is established by X-ray, and subsequent transformations of these initial products to ethinyl or ω-chloroethinyl