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On the mechanism of oxygen-atom or nitrene-group transfer in reactions of epoxides and aziridines with tungsten (II) compounds

…, DE Over, DR McAlister, JM Mayer

文献索引:Atagi, Lauren M.; Over, Diana E.; McAlister, Donald R.; Mayer, James M. Journal of the American Chemical Society, 1991 , vol. 113, # 3 p. 870 - 874

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被引用次数: 58

摘要

... Transfer in Reactions of Epoxides and Aziridines with Tungsten( 11) Compounds Lauren M. Atagi, Diana E. Over, Donald R. McAlister,' and James M. Mayer*** Conrribution from the Department of Chemistry, University of Washington, Seattle, Washington 981 95. Received May 10, 1990 ... 3, 1991 Scheme I Atagi et al. WCI*L, + fi "I ' 1 ... Reduction of epoxides by Cr" and Ti"' has been sug- gested IO proceed through a ring-opened radical. MO- CR2CR2'(M = Cr"'. ...